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Chemistry · 25 min read
Every property of a substance — whether it melts at 800 degrees or at 8, whether it conducts electricity, whether it dissolves in water — follows from how its atoms are bonded. This page connects that one idea to everything that follows from it, which is why it sits between the atomic structure page and the organic chemistry one.
The reactions half is written the way general awareness papers ask it: which indicator turns which colour, what pH means, which metal displaces which, why iron rusts and galvanised iron does not. The physical chemistry needed for entrance papers — gas laws, colligative properties, equilibrium — is given alongside, with the working relations stated.
Current affairs · 19 September 2026
Every item is dated, read on the conducting body’s or ministry’s own site, and written with the question it becomes. Read today’s items, take the quiz, or download the month as a PDF.
Today’s poster
Why it matters
| Exam | Expected questions | How it usually appears |
|---|---|---|
| JEE Main / Advanced | 20–25% of the chemistry paper | Bonding, states of matter, equilibrium and electrochemistry together. |
| NEET Chemistry | 8–10 questions | Bonding and hybridisation are the most reliably asked. |
| SSC CGL / CHSL Tier 1 | 2–3 questions | pH, indicators, common salts and the reactivity series. |
| RRB NTPC / Group D | 2–3 questions | Acids and bases, rusting and everyday chemical names. |
| NDA / CDS General Ability | 2–3 questions | Bond types and simple reaction chemistry. |
Ionic, covalent, metallic and beyond
Atoms bond in order to reach a stable electronic arrangement, usually the noble gas configuration. How they get there — by transferring electrons or by sharing them — determines everything about the resulting substance.
| Property | Ionic compounds | Covalent compounds |
|---|---|---|
| How the bond forms | Complete transfer of electrons from a metal to a non-metal, producing oppositely charged ions held by electrostatic attraction | Sharing of electron pairs between non-metal atoms |
| Physical state | Almost always crystalline solids at room temperature | Often gases or liquids; solids if the molecules are large |
| Melting and boiling points | High, because the ionic lattice is held by strong forces in all directions | Generally low, because the intermolecular forces are weak even though the bonds within a molecule are strong |
| Electrical conductivity | Conduct when molten or dissolved in water, since the ions become free to move; do not conduct as solids | Do not conduct, since there are no free ions or electrons — graphite being the notable exception |
| Solubility | Generally soluble in water and other polar solvents | Generally soluble in organic solvents and insoluble in water |
| Examples | Sodium chloride, magnesium oxide, calcium chloride | Water, methane, carbon dioxide, ammonia |
VSEPR and hybridisation
Shape follows from a single principle: electron pairs around a central atom arrange themselves as far apart as possible, and a lone pair takes more room than a bonding pair.
| Electron pairs | Geometry and hybridisation | Effect of lone pairs |
|---|---|---|
| Two | Linear, 180°, sp hybridised — beryllium chloride, carbon dioxide, acetylene | No lone pairs, so the shape is the geometry. |
| Three | Trigonal planar, 120°, sp² — boron trifluoride, ethene | With one lone pair the shape becomes bent, as in sulphur dioxide. |
| Four | Tetrahedral, 109.5°, sp³ — methane | One lone pair gives a trigonal pyramid, as in ammonia at 107°; two lone pairs give a bent shape, as in water at 104.5°. |
| Five | Trigonal bipyramidal, sp³d — phosphorus pentachloride | Lone pairs occupy equatorial positions, giving see-saw, T-shaped and linear variants. |
| Six | Octahedral, 90°, sp³d² — sulphur hexafluoride | One lone pair gives a square pyramid; two give a square planar shape. |
Gas laws and phase changes
The state of a substance is a contest between intermolecular forces holding particles together and thermal energy driving them apart.
Solubility and colligative properties
A compact topic whose central insight is that some properties of a solution depend only on how many solute particles are present, not on what they are.
The five patterns
Almost every reaction at this level falls into one of five patterns, and identifying the pattern is usually all the question requires.
| Type | What happens | Example |
|---|---|---|
| Combination | Two or more substances form a single product | Quicklime and water give slaked lime, a strongly exothermic reaction used in whitewashing. |
| Decomposition | A single substance breaks into two or more | Calcium carbonate heated gives calcium oxide and carbon dioxide. Decomposition may be thermal, electrolytic or photochemical, as in the darkening of silver bromide in light. |
| Displacement | A more reactive element displaces a less reactive one from its compound | Iron placed in copper sulphate solution displaces copper, and the blue solution turns green. |
| Double displacement | Two compounds exchange ions | Sodium sulphate and barium chloride give a white precipitate of barium sulphate. Neutralisation is a special case. |
| Redox | Electrons are transferred; one species is oxidised and another reduced | The reaction of zinc with copper sulphate is simultaneously a displacement and a redox reaction. |
pH, indicators and neutralisation
The block that supplies more general-awareness questions than any other part of chemistry, because everything in it is something a candidate has handled.
Electron transfer in practice
Oxidation and reduction always occur together, and electrochemistry is simply what happens when the electrons transferred are made to travel through a wire.
Solved examples
Read the steps rather than the answer. The method is what transfers to the next question.
Explain why the bond angle falls from 109.5° in methane to 107° in ammonia and 104.5° in water.
Answer: Increasing lone-pair repulsion compresses the bond angle at each step.
Carbon dioxide has polar bonds but is a non-polar molecule. Why?
Answer: Its linear shape makes the two bond dipoles cancel exactly.
A solution has pH 4. How does its acidity compare with one of pH 6?
Answer: The pH 4 solution is a hundred times more acidic.
Why does galvanised iron resist rusting even where the zinc coating is scratched?
Answer: Zinc is more reactive and corrodes sacrificially in place of the iron.
Why does copper not liberate hydrogen from dilute hydrochloric acid while zinc does?
Answer: Copper is below hydrogen in the reactivity series and zinc is above it.
Why does the temperature stay constant while ice melts, even though heat is being supplied?
Answer: The heat supplied goes into breaking intermolecular forces rather than raising kinetic energy.
A gas is compressed to half its volume at constant temperature. What happens to its pressure?
Answer: The pressure doubles.
Why is salt spread on icy roads?
Answer: It depresses the freezing point of water, a colligative property.
Practice
Work each one out before you reveal the answer — the explanation is where the marks are.
Q1An ionic compound conducts electricity when:
Q2The bond angle in a water molecule is approximately:
Q3The hybridisation of carbon in methane is:
Q4The unusually high boiling point of water is due to:
Q5Boyle's law relates:
Q6Phenolphthalein in a basic solution is:
Q7A pH of 3 indicates a solution that is:
Q8Oxidation is defined as:
Q9Which metal is used for galvanising iron?
Q10Plaster of Paris is obtained by heating:
Q11The Tyndall effect is shown by:
Q12A catalyst increases the rate of a reaction by:
Q13Freezing point depression is an example of a:
Q14In an electrolytic cell, reduction occurs at the:
Q15Sulphur hexafluoride is an exception to the octet rule because sulphur:
Q16Which gas turns limewater milky?
Questions
Because an ionic solid is not made of molecules at all — it is a giant three-dimensional lattice in which every ion is held by strong electrostatic attraction to all its oppositely charged neighbours. Melting requires breaking that whole network. A covalent substance such as water consists of discrete molecules with strong bonds inside but weak forces between them, and only those weak forces must be overcome to melt it.
Strength describes how completely the acid ionises in water — a property of the substance. Concentration describes how much of it is dissolved — a property of the solution. Hydrochloric acid is strong at any concentration, and a very dilute solution of it can have a higher pH than a concentrated solution of weak acetic acid. Question papers exploit this distinction regularly.
Because a lone pair is attracted by only one nucleus while a bonding pair is shared between two. The lone pair therefore occupies a larger, more diffuse region close to the central atom and repels the bonding pairs more strongly than they repel one another. The order of repulsion is lone pair-lone pair greater than lone pair-bond pair greater than bond pair-bond pair.
Because it is strong enough to change physical properties dramatically while being weak enough to be broken and re-formed constantly. It is why water is a liquid at room temperature when similar-sized molecules are gases, why ice floats and lakes freeze from the top, why DNA strands hold together yet can be separated for replication, and why proteins fold into specific shapes. Almost every anomaly of water traces back to it.
No. A catalyst speeds up both the forward and the backward reaction equally, so it brings a system to equilibrium faster but does not change where that equilibrium lies. To change the yield you must change conditions — concentration, pressure or temperature — as Le Chatelier's principle describes, which is exactly what the Haber and Contact processes do.
Because the molecules that escape from the surface are the fastest-moving ones, with the most energy. Removing them lowers the average kinetic energy of those left behind, and average kinetic energy is what temperature measures. This is why sweating cools the body, why water in a porous earthen pot stays cool, and why a volatile liquid such as ether feels cold on the skin.
Protecting a metal by connecting it to a more reactive one, which corrodes preferentially. Galvanised iron is the everyday case: the zinc coating oxidises rather than the iron, and continues to protect even where the coating is scratched, unlike paint. Blocks of magnesium or zinc are attached to ships' hulls and to buried pipelines for the same reason.
Acids, bases and pH; indicators and their colours; the common salts and their uses; rusting and its prevention; the reactivity series; and simple bond types. Hybridisation, VSEPR geometry beyond the basic shapes, gas law calculations, colligative property numericals and electrochemistry belong to JEE and NEET.
Because each carbon atom in graphite bonds to only three others, leaving one electron per atom delocalised across the layer. Those mobile electrons make graphite a conductor, which no ordinary covalent solid is. The layers themselves are held only by weak forces, which is why graphite is soft and slippery — and why it works as both an electrode and a lubricant.
Roughly twenty to twenty-five per cent of JEE chemistry, counting bonding, states of matter, equilibrium and electrochemistry; eight to ten questions in NEET; two to three in SSC CGL Tier 1, mostly on acids and bases; two to three in RRB; and two to three in NDA and CDS.
Attempt a timed mock while the formulas are fresh — that is what tells you which of them actually stuck.
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