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Chemistry · 25 min read
Carbon forms more compounds than every other element combined, and the reason is a single property: it can bond to itself indefinitely, in chains, branches and rings, while still bonding to four other atoms. Once that is clear, organic chemistry stops being a list of compounds and becomes a set of families with predictable behaviour.
The second half of this page is the applied chemistry that general-awareness papers ask about most heavily — soaps and detergents, plastics, medicines, food preservatives and fuels. Almost every one of those questions is answered by knowing which functional group or which polymer type is involved.
Current affairs · 19 September 2026
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Today’s poster
Why it matters
| Exam | Expected questions | How it usually appears |
|---|---|---|
| JEE Main / Advanced | 25–30% of the chemistry paper | Organic chemistry is the largest of the three branches in the paper. |
| NEET Chemistry | 10–14 questions | Including biomolecules, which overlap with the biology syllabus. |
| SSC CGL / CHSL Tier 1 | 2–3 questions | Everyday applications — plastics, medicines, fuels and food chemistry. |
| RRB NTPC / Group D | 2–3 questions | Common compounds, their uses and their common names. |
| NDA / CDS General Ability | 1–2 questions | Hydrocarbons and applied chemistry at school level. |
Why carbon is unique
Two properties account for the entire existence of organic chemistry as a separate branch, and the allotropes of carbon then demonstrate how differently the same atoms can behave when arranged differently.
| Allotrope | Structure | Properties and uses |
|---|---|---|
| Diamond | Each carbon bonded to four others in a rigid three-dimensional tetrahedral network, sp³ hybridised | The hardest natural substance and an electrical insulator, since all four electrons are committed to bonds. Used in cutting, drilling and abrasives, and as gemstones. |
| Graphite | Layers of hexagonal rings, each carbon bonded to three others, sp² hybridised, with layers held by weak forces | Soft and slippery because the layers slide, and a good conductor because one electron per atom is delocalised. Used as a lubricant, in pencils and as an electrode. |
| Fullerene | Closed cages of carbon atoms; buckminsterfullerene, C₆₀, has the shape of a football | Discovered in 1985 and named after the architect Buckminster Fuller. Of research interest in drug delivery and materials. |
| Graphene | A single one-atom-thick layer of graphite | Exceptionally strong, an excellent conductor of heat and electricity, and nearly transparent. A major materials research subject. |
| Carbon nanotubes | Graphene sheets rolled into cylinders | Extremely high tensile strength and useful electrical properties, depending on how the sheet is rolled. |
Diamond is the hardest substance known and graphite is one of the softest; diamond insulates and graphite conducts; diamond is transparent and graphite opaque. Both are pure carbon. The difference is entirely in the bonding arrangement, which is the clearest possible demonstration that structure determines property — and it is asked as a comparison almost every year.
Alkanes, alkenes, alkynes, aromatics
Compounds of carbon and hydrogen alone, divided by whether they contain only single bonds or also multiple ones. That single distinction determines how they react.
| Family | General formula | Bonding and reactivity |
|---|---|---|
| Alkanes | CₙH₂ₙ₊₂ | Saturated — only single bonds. Relatively unreactive, undergoing substitution rather than addition. Methane, ethane, propane, butane. Also called paraffins, from the Latin for "little affinity". |
| Alkenes | CₙH₂ₙ | One carbon-carbon double bond. Unsaturated and reactive, undergoing addition reactions. Ethene is the simplest, and is used to ripen fruit and to make polythene. |
| Alkynes | CₙH₂ₙ₋₂ | One carbon-carbon triple bond. More unsaturated still. Ethyne, or acetylene, burns with oxygen at a very high temperature and is used for welding. |
| Aromatics | Based on the benzene ring, C₆H₆ | A planar six-carbon ring with delocalised electrons. Despite being highly unsaturated, benzene resists addition and prefers substitution, because addition would destroy the stable delocalised system. |
Families, naming and isomerism
A functional group is the reactive part of a molecule, and it determines the compound's chemistry almost entirely regardless of the size of the carbon chain attached to it.
| Group | Formula and suffix | Example and use |
|---|---|---|
| Alcohol | −OH, suffix -ol | Ethanol, in alcoholic drinks, as a solvent and as a fuel additive. Methanol is highly toxic and causes blindness. |
| Aldehyde | −CHO, suffix -al | Methanal, or formaldehyde, used as a preservative for biological specimens as formalin. |
| Ketone | >C=O within the chain, suffix -one | Propanone, or acetone, a common solvent and nail-polish remover. |
| Carboxylic acid | −COOH, suffix -oic acid | Ethanoic acid, the acid in vinegar at five to eight per cent. Pure ethanoic acid freezes at about 17 °C and is called glacial acetic acid. |
| Ester | −COO−, suffix -oate | Formed from an acid and an alcohol; esters have pleasant fruity smells and are used in perfumes and flavourings. |
| Amine | −NH₂, suffix -amine | The basis of amino acids and of many drugs and dyes. |
| Halide | −X, prefix halo- | Chloroform, once an anaesthetic; chlorofluorocarbons, now phased out because they deplete stratospheric ozone. |
The reactions actually asked
A short list of reaction types accounts for nearly every organic question at this level, and each has a familiar industrial or domestic application.
A soap molecule has a long non-polar hydrocarbon tail and an ionic head. In water the molecules form micelles with the tails inward around a droplet of grease and the heads outward, which is how dirt is lifted and suspended. In hard water, containing calcium and magnesium ions, soap forms an insoluble scum instead of a lather and is wasted. Synthetic detergents have sulphonate or sulphate heads whose calcium and magnesium salts are soluble, so they work in hard water — which is the whole reason they were developed.
Carbohydrates, proteins, fats
The organic chemistry of living systems, shared with the biology syllabus and asked in both.
| Class | Building block | Examples and function |
|---|---|---|
| Carbohydrates | Monosaccharides such as glucose and fructose | Disaccharides — sucrose from glucose and fructose, lactose in milk, maltose. Polysaccharides — starch, the plant storage form; glycogen, the animal storage form; and cellulose, the structural polymer of plant cell walls, which humans cannot digest. The primary energy source, giving about four kilocalories per gram. |
| Proteins | Amino acids, of which twenty occur in proteins, joined by peptide bonds | Enzymes, antibodies, haemoglobin, structural proteins such as collagen and keratin. Nine amino acids are essential, meaning the body cannot synthesise them and they must come from food. Deficiency causes kwashiorkor. |
| Lipids | Fatty acids and glycerol | Fats and oils store energy at about nine kilocalories per gram, the most energy-dense nutrient. Saturated fats are solid and mostly of animal origin; unsaturated fats are liquid oils. Phospholipids form cell membranes and cholesterol is a steroid precursor. |
| Nucleic acids | Nucleotides — a sugar, a phosphate and a nitrogenous base | DNA carries genetic information as a double helix with adenine pairing to thymine and guanine to cytosine. RNA is single-stranded, uses uracil in place of thymine, and carries out protein synthesis. |
Plastics, fibres and rubber
Large molecules built by joining many small repeating units, and one of the areas of chemistry that most directly changed daily life — and the environment.
| Polymer | Type and monomer | Uses |
|---|---|---|
| Polythene | Addition polymer of ethene | Bags, packaging film, bottles, pipes. The commonest plastic by volume. |
| PVC | Addition polymer of vinyl chloride | Pipes, cable insulation, flooring, upholstery. |
| Polystyrene | Addition polymer of styrene | Disposable cups and packaging; the expanded form is thermocol. |
| Teflon | Addition polymer of tetrafluoroethene | Non-stick cookware coatings and chemically resistant seals. |
| Nylon | Condensation polymer of a diamine and a dicarboxylic acid | Ropes, textiles, parachutes, brushes. The first fully synthetic fibre. |
| Terylene or polyester | Condensation polymer of ethylene glycol and terephthalic acid | Fabrics and, as PET, drink bottles — the most widely recycled plastic. |
| Bakelite | Condensation polymer of phenol and formaldehyde | Electrical switches and handles; the first fully synthetic plastic, and thermosetting. |
Medicines, food and fuels
The applied section, which supplies the majority of the chemistry questions in general awareness papers because every item in it is familiar.
Solved examples
Read the steps rather than the answer. The method is what transfers to the next question.
Diamond and graphite are both pure carbon. Why is one hard and insulating and the other soft and conducting?
Answer: Their bonding arrangement differs — three-dimensional network against weakly held layers.
How is vanaspati made from vegetable oil, and what is the reaction called?
Answer: Hydrogenation — an addition reaction using a nickel catalyst.
Why does soap fail to lather in hard water while detergent works?
Answer: Soap forms insoluble calcium and magnesium salts; detergent's equivalents are soluble.
Why does wine left open turn sour?
Answer: Ethanol is oxidised by air to ethanoic acid.
Distinguish a thermoplastic from a thermosetting plastic, with examples.
Answer: Thermoplastics remould; thermosets set permanently because their chains are cross-linked.
What is vulcanisation and why is it done?
Answer: Heating rubber with sulphur to cross-link the chains, making it strong and temperature-stable.
Why do antibiotics not work against a common cold?
Answer: A cold is viral, and antibiotics act only on bacterial structures.
C₂H₆O can be either ethanol or dimethyl ether. What kind of isomerism is this?
Answer: Functional isomerism.
Practice
Work each one out before you reveal the answer — the explanation is where the marks are.
Q1The general formula of alkanes is:
Q2The hardest naturally occurring substance is:
Q3Successive members of a homologous series differ by:
Q4The functional group −COOH belongs to:
Q5Conversion of vegetable oil to vanaspati is an example of:
Q6Which alcohol is highly toxic and causes blindness?
Q7Soap is a:
Q8Bakelite is a:
Q9Nylon is an example of a:
Q10Vulcanisation of rubber involves heating it with:
Q11The polysaccharide humans cannot digest is:
Q12Penicillin was discovered by:
Q13An antiseptic differs from a disinfectant in that it is:
Q14Which fuel has the highest calorific value?
Q15Ethanol and dimethyl ether, both C₂H₆O, illustrate:
Q16Buckminsterfullerene, C₆₀, has the shape of a:
Questions
Two reasons acting together. Catenation — carbon's ability to bond to itself in chains, branches and rings of unlimited length, made possible by the exceptional strength of the carbon-carbon bond. And tetravalency — four bonds per atom, which allows an enormous number of distinct arrangements. Add isomerism, where the same atoms can be arranged differently, and the number of possible compounds becomes effectively unlimited.
A saturated compound has only single carbon-carbon bonds and cannot add more atoms, so it reacts by substitution. An unsaturated one has a double or triple bond and reacts readily by addition. Practically, unsaturated compounds burn with a sooty yellow flame, decolourise bromine water, and — in the case of fats — are liquid at room temperature and generally considered healthier than saturated fats.
Because only thermoplastics can be melted and remoulded. Their chains are separate, held by weak forces, so heat softens them reversibly. Thermosetting plastics are cross-linked into a single rigid network during moulding, so heating chars rather than softens them. Add contamination and mixed polymer types, and mechanical recycling becomes harder still — which is why reduction rather than recycling is the priority in the waste hierarchy.
Because of what their calcium and magnesium salts do. Soap is a fatty acid salt, and its calcium and magnesium salts are insoluble, so in hard water it precipitates as scum instead of lathering. Detergents have sulphonate or sulphate head groups whose calcium and magnesium salts remain soluble, so they lather regardless. This solved a real domestic problem and is why detergents were developed.
A spherical cluster of soap or detergent molecules with their non-polar hydrocarbon tails pointing inward and their ionic heads outward. Grease dissolves in the non-polar interior while the ionic surface keeps the whole cluster suspended in water. That dual nature — one end attracted to oil, the other to water — is the entire principle of cleaning.
Because biological receptors are themselves chiral, so two optical isomers of a drug can fit differently and behave quite differently in the body — one may be therapeutic and the other inactive or harmful. This is why many modern drugs are manufactured as a single isomer rather than as a mixture, and why the distinction matters far beyond the chemistry classroom.
No. Antibiotics target structures and processes unique to bacteria — the cell wall, bacterial ribosomes, bacterial enzymes. Viruses have none of these; they reproduce using the host cell's own machinery. Taking antibiotics for a cold or influenza therefore achieves nothing and drives resistance in whatever bacteria happen to be present. Antivirals are a separate class of drug.
The applied section almost entirely — plastics and their types, soaps and detergents, vulcanisation, classes of medicine, food preservatives and sweeteners, fuels and their calorific values, and the allotropes of carbon. IUPAC nomenclature, reaction mechanisms, isomer counting and biomolecule structures belong to JEE and NEET.
Its delocalised electron system. In benzene the six electrons that would form three separate double bonds are spread evenly around the ring, and that arrangement is unusually stable. An addition reaction would destroy the delocalisation and lose that stability, so benzene prefers substitution, which keeps the ring intact. This resistance to addition is what defines aromatic character.
Around a quarter to a third of JEE, making it the largest of the three branches in that paper; ten to fourteen questions in NEET, including biomolecules; two to three in SSC CGL Tier 1 and in RRB, almost all of them from the everyday applications; and one to two in NDA and CDS.
Attempt a timed mock while the formulas are fresh — that is what tells you which of them actually stuck.
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